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Air pollution is a general term that covers a broad range of contaminants in the atmosphere. Pollution can occur from natural causes or from human activities. Discussions about the effects of air pollution have focused mainly on human health but attention is being directed to environmental quality and amenity as well. Air pollutants are found as gases or particles, and on a restricted scale they can be trapped inside buildings as indoor air pollutants. Urban air pollution has long been an important concern for civic administrators, but increasingly, air pollution has become an international problem.
The most characteristic sources of air pollution have always been combustion processes. Here the most obvious pollutant is smoke. However, the widespread use of fossil fuels has made sulfur and nitrogen oxides pollutants of great concern. With increasing use of petroleum-based fuels, a range of organic compounds have become widespread in the atmosphere.
In urban areas, air pollution has been a matter of concern since historical times. Indeed, there were complaints about smoke in ancient Rome. The use of coal throughout the centuries has caused cities to be very smoky places. Along with smoke, large concentrations of sulfur dioxide were produced. It was this mixture of smoke and sulfur dioxide that typified the foggy streets of Victorian London, paced by such figures as Sherlock Holmes and Jack the Ripper, whose images remain linked with smoke and fog. Such situations are far less common in the cities of North America and Europe today. However, until recently, they have been evident in other cities, such as Ankara, Turkey, and Shanghai, China, that rely heavily on coal.
Coal is still burned in large quantities to produce electricity or to refine metals, but these processes are frequently undertaken outside cities. Within urban areas, fuel use has shifted toward liquid and gaseous hydrocarbons (petroleum and natural gas). These fuels typically have a lower concentration of sulfur, so the presence of sulfur dioxide has declined in many urban areas. However, the widespread use of liquid fuels in automobiles has meant increased production of carbon monoxide, nitrogen oxides, and volatile organic compounds.
Primary pollutants such as sulfur dioxide or smoke are the direct emission products of the combustion process. Today, many of the key pollutants in the urban atmospheres are secondary pollutants, produced by processes initiated through photochemical reactions. The Los Angeles, California-type, photochemical smog is now characteristic of urban atmospheres dominated by secondary pollutants.
Although the automobile is the main source of air pollution in contemporary cities, there are other equally significant sources. Stationary sources are still important and the oil-burning furnaces that have replaced the older coal-burning ones are still responsible for a range of gaseous emissions and fly ash. Incineration is also an important source of complex combustion products, especially where this incineration burns a wide range of refuse. These emissions can include chlorinated hydrocarbons such as dioxin. When plastics, which often contain chlorine, are incinerated, hydrochloric acid is found in the waste gas stream. Metals, especially since they are volatile at high temperatures, can migrate to smaller, respirable particles. The accumulation of toxic metals, such as cadmium, on fly ash gives rise to concern over harmful effects from incinerator emissions. In specialized incinerators designed to destroy toxic compounds such as polychlorinated biphenyls (PCBs), many questions have been raised about the completeness of this destruction process. Even under optimum conditions when the furnace operation has been properly maintained, great care needs to be taken to control leaks and losses during transfer operations (fugitive emissions).
The enormous range of compounds used in modern manufacturing processes has also meant that there is an ever-widening range of emissions from both the industrial processes and the combustion of their wastes. Although the amounts of these toxic compounds are often rather small, they add to the complex range of compounds found in the urban atmosphere. Again, it is not only the deliberate loss of effluents through discharge from pipes and chimneys that needs attention. Fugitive emissions of volatile substances that leak from valves and seals often warrant careful control.
Air pollution control procedures are increasingly an important part of civic administration, although their goals are far from easy to achieve. It is also noticeable that although many urban concentrations of primary pollutants, for example, smoke and sulfur dioxide, are on the decline in developed countries, this is not always true in developing countries. Here the desire for rapid industrial growth has often lowered urban air quality. Secondary air pollutants are generally proving a more difficult problem to eliminate than primary pollutants like smoke.
AIR POLLUTION AND HEALTH PROBLEMS
Urban air pollutants have a wide range of effects, with health problems being the most enduring concern. In the classical polluted atmospheres filled with smoke and sulfur dioxide, a range of bronchial diseases was enhanced. While respiratory diseases are still the principal problem, the issues are somewhat more subtle in atmospheres where the air pollutants are not so obvious. In photo-chemical smog, eye irritation from a secondary pollutant, peroxyacetyl nitrate (PAN), is one of the most characteristic direct effects of the smog. High concentrations of carbon monoxide in cities where automobiles operate at high density mean that the human heart has to work harder to make up for the oxygen displaced from the blood's hemoglobin by carbon monoxide. This extra stress appears to reveal itself through increased incidence of complaints among people with heart problems. There is a widespread belief that contemporary air pollutants are involved in the increases in asthma, but the links between asthma and air pollution are probably rather complex and related to a whole range of factors. Lead, from automotive exhausts, is thought by many to be a factor in lowering the IQs of urban children.
Air pollution also affects materials in the urban environment. Soiling has long been regarded as a problem, originally the result of the smoke from wood or coal fires, but now increasingly the result of fine black soot from diesel exhausts. The acid gases, particularly sulfur dioxide, increase the rate of destruction of building materials. This is most noticeable with calcareous stones, which are the predominant building material of many important historic structures. Metals also suffer from atmospheric acidity. In today's photochemical smog, natural rubbers crack and deteriorate rapidly.
Health problems relating to indoor air pollution are extremely ancient. Anthracosis, or black lung disease, has been found in mummified lung tissue. Recent decades have witnessed a shift from the predominance of concern about outdoor air pollution into a widening interest in indoor air quality.
The production of energy from combustion and the release of solvents is so large in the contemporary world that it causes air pollution problems of regional and global nature. Acid rain is now widely observed throughout the world. The sheer quantity of carbon dioxide emitted in combustion processes is increasing the concentration of carbon dioxide in the atmosphere and enhancing the greenhouse effect. Solvents, such as carbon tetrachloride and the aerosol propellants chlorofluorocarbons (CFCs) are now detectable all over the globe and responsible for problems such as ozone layer depletion.
At the other end of the scale, we need to remember that gases leak indoors from the polluted outdoor environment, but more often the serious pollutants arise from processes that take place indoors. Here there has been particular concern with regards to the generation of nitrogen oxides by sources such as gas stoves. Similarly, formaldehyde from insulating foams causes illnesses and adds to concerns about our exposure to a substance that may induce cancer in the long run. In the last decade it has become clear that radon leaks from the ground can expose some members of the public to high levels of this radioactive gas within their own homes. Cancers may also result from the emanation of solvents from consumer products—glues, paints, and mineral fibers (asbestos). More generally these compounds and a range of biological materials—animal hair, skin, pollen spores, and dusts—can cause allergic reactions in some people. At one end of the spectrum these simply cause annoyance, but in extreme cases, such as found with the bacterium Legionella, a large number of deaths can occur.
There are also important issues surrounding the effects of indoor air pollutants on materials. Many industries, especially the electronics industry, must take great care over the purity of indoor air where a speck of dust can destroy a microchip or low concentrations of air pollutants change the composition of surface films in component design. Museums must care for objects over long periods of time, so precautions must be taken to protect delicate dyes from the effects of photochemical smog, paper and books from sulfur dioxide, and metals from sulfide gases.
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What Do you Know About Air Pollution
Air pollution is a general term that covers a broad range of contaminants in the atmosphere. Pollution can occur from natural causes or from human activities. Discussions about the effects of air pollution have focused mainly on human health but attention is being directed to environmental quality and amenity as well. Air pollutants are found as gases or particles, and on a restricted scale they can be trapped inside buildings as indoor air pollutants. Urban air pollution has long been an important concern for civic administrators, but increasingly, air pollution has become an international problem.
The most characteristic sources of air pollution have always been combustion processes. Here the most obvious pollutant is smoke. However, the widespread use of fossil fuels has made sulfur and nitrogen oxides pollutants of great concern. With increasing use of petroleum-based fuels, a range of organic compounds have become widespread in the atmosphere.
In urban areas, air pollution has been a matter of concern since historical times. Indeed, there were complaints about smoke in ancient Rome. The use of coal throughout the centuries has caused cities to be very smoky places. Along with smoke, large concentrations of sulfur dioxide were produced. It was this mixture of smoke and sulfur dioxide that typified the foggy streets of Victorian London, paced by such figures as Sherlock Holmes and Jack the Ripper, whose images remain linked with smoke and fog. Such situations are far less common in the cities of North America and Europe today. However, until recently, they have been evident in other cities, such as Ankara, Turkey, and Shanghai, China, that rely heavily on coal.
Coal is still burned in large quantities to produce electricity or to refine metals, but these processes are frequently undertaken outside cities. Within urban areas, fuel use has shifted toward liquid and gaseous hydrocarbons (petroleum and natural gas). These fuels typically have a lower concentration of sulfur, so the presence of sulfur dioxide has declined in many urban areas. However, the widespread use of liquid fuels in automobiles has meant increased production of carbon monoxide, nitrogen oxides, and volatile organic compounds.
Primary pollutants such as sulfur dioxide or smoke are the direct emission products of the combustion process. Today, many of the key pollutants in the urban atmospheres are secondary pollutants, produced by processes initiated through photochemical reactions. The Los Angeles, California-type, photochemical smog is now characteristic of urban atmospheres dominated by secondary pollutants.
Although the automobile is the main source of air pollution in contemporary cities, there are other equally significant sources. Stationary sources are still important and the oil-burning furnaces that have replaced the older coal-burning ones are still responsible for a range of gaseous emissions and fly ash. Incineration is also an important source of complex combustion products, especially where this incineration burns a wide range of refuse. These emissions can include chlorinated hydrocarbons such as dioxin. When plastics, which often contain chlorine, are incinerated, hydrochloric acid is found in the waste gas stream. Metals, especially since they are volatile at high temperatures, can migrate to smaller, respirable particles. The accumulation of toxic metals, such as cadmium, on fly ash gives rise to concern over harmful effects from incinerator emissions. In specialized incinerators designed to destroy toxic compounds such as polychlorinated biphenyls (PCBs), many questions have been raised about the completeness of this destruction process. Even under optimum conditions when the furnace operation has been properly maintained, great care needs to be taken to control leaks and losses during transfer operations (fugitive emissions).
The enormous range of compounds used in modern manufacturing processes has also meant that there is an ever-widening range of emissions from both the industrial processes and the combustion of their wastes. Although the amounts of these toxic compounds are often rather small, they add to the complex range of compounds found in the urban atmosphere. Again, it is not only the deliberate loss of effluents through discharge from pipes and chimneys that needs attention. Fugitive emissions of volatile substances that leak from valves and seals often warrant careful control.
Air pollution control procedures are increasingly an important part of civic administration, although their goals are far from easy to achieve. It is also noticeable that although many urban concentrations of primary pollutants, for example, smoke and sulfur dioxide, are on the decline in developed countries, this is not always true in developing countries. Here the desire for rapid industrial growth has often lowered urban air quality. Secondary air pollutants are generally proving a more difficult problem to eliminate than primary pollutants like smoke.
AIR POLLUTION AND HEALTH PROBLEMS
Urban air pollutants have a wide range of effects, with health problems being the most enduring concern. In the classical polluted atmospheres filled with smoke and sulfur dioxide, a range of bronchial diseases was enhanced. While respiratory diseases are still the principal problem, the issues are somewhat more subtle in atmospheres where the air pollutants are not so obvious. In photo-chemical smog, eye irritation from a secondary pollutant, peroxyacetyl nitrate (PAN), is one of the most characteristic direct effects of the smog. High concentrations of carbon monoxide in cities where automobiles operate at high density mean that the human heart has to work harder to make up for the oxygen displaced from the blood's hemoglobin by carbon monoxide. This extra stress appears to reveal itself through increased incidence of complaints among people with heart problems. There is a widespread belief that contemporary air pollutants are involved in the increases in asthma, but the links between asthma and air pollution are probably rather complex and related to a whole range of factors. Lead, from automotive exhausts, is thought by many to be a factor in lowering the IQs of urban children.
Air pollution also affects materials in the urban environment. Soiling has long been regarded as a problem, originally the result of the smoke from wood or coal fires, but now increasingly the result of fine black soot from diesel exhausts. The acid gases, particularly sulfur dioxide, increase the rate of destruction of building materials. This is most noticeable with calcareous stones, which are the predominant building material of many important historic structures. Metals also suffer from atmospheric acidity. In today's photochemical smog, natural rubbers crack and deteriorate rapidly.
Health problems relating to indoor air pollution are extremely ancient. Anthracosis, or black lung disease, has been found in mummified lung tissue. Recent decades have witnessed a shift from the predominance of concern about outdoor air pollution into a widening interest in indoor air quality.
The production of energy from combustion and the release of solvents is so large in the contemporary world that it causes air pollution problems of regional and global nature. Acid rain is now widely observed throughout the world. The sheer quantity of carbon dioxide emitted in combustion processes is increasing the concentration of carbon dioxide in the atmosphere and enhancing the greenhouse effect. Solvents, such as carbon tetrachloride and the aerosol propellants chlorofluorocarbons (CFCs) are now detectable all over the globe and responsible for problems such as ozone layer depletion.
At the other end of the scale, we need to remember that gases leak indoors from the polluted outdoor environment, but more often the serious pollutants arise from processes that take place indoors. Here there has been particular concern with regards to the generation of nitrogen oxides by sources such as gas stoves. Similarly, formaldehyde from insulating foams causes illnesses and adds to concerns about our exposure to a substance that may induce cancer in the long run. In the last decade it has become clear that radon leaks from the ground can expose some members of the public to high levels of this radioactive gas within their own homes. Cancers may also result from the emanation of solvents from consumer products—glues, paints, and mineral fibers (asbestos). More generally these compounds and a range of biological materials—animal hair, skin, pollen spores, and dusts—can cause allergic reactions in some people. At one end of the spectrum these simply cause annoyance, but in extreme cases, such as found with the bacterium Legionella, a large number of deaths can occur.
There are also important issues surrounding the effects of indoor air pollutants on materials. Many industries, especially the electronics industry, must take great care over the purity of indoor air where a speck of dust can destroy a microchip or low concentrations of air pollutants change the composition of surface films in component design. Museums must care for objects over long periods of time, so precautions must be taken to protect delicate dyes from the effects of photochemical smog, paper and books from sulfur dioxide, and metals from sulfide gases.
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